The Wonderful 101 and Bayonetta both stand out immediately to me. Other games like Dark Souls and Bloodborne come close but FROM always seem to add at one or two awful boss fights for god knows what reason.
I love DOOM, but it has only three bosses. The Cyberdemon was awesome and the Spider Mastermind was pretty darn good, but the Hell Guard dudes were boring, easy, and forgettable. That's a third of the bosses!
And on the sixth day the LORD David Bowie created man and woman in His image. And he saw that it was good. On the seventh day the LORD created videogames so that He might take the bloody day off for once.