Bane has a presence and swagger about him that's unmatched in the trilogy. He towers over people, he imitates with a glare, he's pretty much never out of control of the situation. He's lays his hand near old guy's head and it's understood just out of his league corporate suit guy is. "Does it look like you're in any position of power here?"
However, he doesn't have the moment-to-moment spontaneous, chaotic fun that the Joker has, instead replaced with straight ahead villiany and garbled, sometimes flat-out unintelligible dialog. I also think thematically he's a weaker, less ambitious character then The Joker, and at times feels like a reheated mish-mash of Ra's and The Joker instead of his own unique antagonist. And finally, his final scenes are disappointing, not just in the way he loses(dude totally dominated Batman, but he comes back and manages to cut part of his mask, and he's done?), but Talia's sudden ascendance demotes him down to sidekick/big bodyguard status, and then suddenly taking off the board by Catwoman. His arc doesn't so much end as it just flips, and then stops suddenly.
If I had to rank the head bad guys, it'd be Joker >> Bane > Ra's.